全文获取类型
收费全文 | 2545篇 |
免费 | 91篇 |
国内免费 | 11篇 |
专业分类
化学 | 1966篇 |
晶体学 | 26篇 |
力学 | 31篇 |
数学 | 180篇 |
物理学 | 444篇 |
出版年
2021年 | 19篇 |
2020年 | 39篇 |
2019年 | 57篇 |
2018年 | 30篇 |
2017年 | 27篇 |
2016年 | 52篇 |
2015年 | 39篇 |
2014年 | 44篇 |
2013年 | 121篇 |
2012年 | 144篇 |
2011年 | 144篇 |
2010年 | 69篇 |
2009年 | 82篇 |
2008年 | 132篇 |
2007年 | 128篇 |
2006年 | 144篇 |
2005年 | 117篇 |
2004年 | 76篇 |
2003年 | 88篇 |
2002年 | 93篇 |
2001年 | 55篇 |
2000年 | 40篇 |
1999年 | 30篇 |
1998年 | 31篇 |
1997年 | 25篇 |
1996年 | 22篇 |
1995年 | 16篇 |
1994年 | 14篇 |
1993年 | 26篇 |
1992年 | 31篇 |
1991年 | 31篇 |
1990年 | 37篇 |
1989年 | 27篇 |
1988年 | 28篇 |
1987年 | 27篇 |
1986年 | 36篇 |
1985年 | 35篇 |
1984年 | 46篇 |
1983年 | 33篇 |
1982年 | 36篇 |
1981年 | 35篇 |
1980年 | 35篇 |
1979年 | 29篇 |
1978年 | 36篇 |
1977年 | 31篇 |
1976年 | 21篇 |
1975年 | 20篇 |
1974年 | 23篇 |
1973年 | 24篇 |
1972年 | 14篇 |
排序方式: 共有2647条查询结果,搜索用时 15 毫秒
81.
Tomio Shimizu Yoshiyuki Hayashi Takehiro Taniguchi Kazuhiro Teramura 《Tetrahedron》1985,41(4):727-738
A variety of symmetrically or unsymmetrically 3,4-disubstituttd furoxans such as dicyano, dialkyl, diacyl, bis(phenylsulfonyl), N.N'-dialkyldicarbamoyl, 3(or 4)-methyl-4(or -3)-phenyl(or nitro, ethoxy, phenoxy, phenylthio, pyrrolidinyl, phenylsulfonyl), 3(or 4)-ethyl-4(or -3)phcnyl, and 3(or 4)-ethoxy-4(or -3)-phenylsulfonylruroxan reacted with dipolarophiles in toluene or xylene at the refluxing temperature to give nitrone-type 1,3-dipolar cycloadducts, 5-substituted 1-aza-2,8-dioxabicyclo-[3.3.0]octanes and/or 3-substituted 2-isoxazoline 2-oxides. On the other hand, some of the furoxans gave 2-isoxazolines via nitrile oxide 1,3-dipolar cycloaddition in a toluene (or xylene)-DMF solvent at the refluxing temperature. 相似文献
82.
Masahiro Fujita Hiroshi Egawa Katsumi Chiba Jun-Ichi Matsumoto 《Journal of heterocyclic chemistry》1997,34(6):1731-1735
The one-pot reaction of ethyl 1-cyclopropyl-6,7,8-trifluoro-1,4-dihydro-4-oxoquinoline-3-carboxylate ( 6 ) with tert-butyl acetoacetate gave 3-tert-butyl 7-ethyl 9-cyclopropyl-4-fluoro-6,9-dihydro-2-methyl-6-oxofuro[3,2-h]quinoline-3,7-dicarboxylate ( 5 ). This regioselective cyclization was rationalized by the Hard and Soft Acids and Bases principle. By use of a similar furan-forming reaction, we prepared 2-(amino-methyl)furo[3,2-h]quinoline-7-carboxylic acid 4 . Compound 4 showed weak antibacterial activity. 相似文献
83.
High enantioselectivity in rhodium-catalyzed allylic alkylation of 1-substituted 2-propenyl acetates
[reaction: see text] Rhodium-catalyzed asymmetric allylic alkylation of 1-substituted 2-propenyl acetates with dimethyl malonate proceeded with high enantioselectivity in the presence of cesium carbonate as a base and a rhodium catalyst generated from Rh(dpm)(C(2)H(4))(2) (dpm = dipivaloylmethanato) and a chiral phosphino-oxazoline whose basic skeleton is axially chiral binaphthyl to give branch alkylation products in greater than 90% ee. 相似文献
84.
When milled together with bismuth shot in the presence of allyl halide, aromatic aldehydes readily underwent a Barbier-type allylation to afford the corresponding homoallyl alcohols in good yield. In contrast to the failure in solution reaction, aromatic ketones also underwent allylic carbonyl addition under solvent-free conditions to give the expected tertiary homoallyl alcohols in moderate to good yield. 相似文献
85.
Shunsuke Hayashi Takashi Ishikawa Tatsuo Asai Colin Turnbull Kanzo Sakata Koji Ogawa 《Tetrahedron》2004,60(33):7005-7013
The hydrolysis of 2-phenylethyl β-d-glucopyranoside (3) was found to be partially inhibited by feeding with 2-phenyl-N-glucosyl-acetamidiumbromide (8), a β-glucosidase inhibitor, resulting in a decrease in the diurnal emission of 2-phenylethanol (2) from Rosa damascena Mill. flowers. Detection of [1,1,2,2′,3′,4′,5′,6′-2H8]-2 and [1,2,2′,3′,4′,5′,6′-2H7]-2 from R. ‘Hoh-Jun’ flowers fed with [1,1,2,2′,3′,4′,5′,6′-2H8]-3 suggested that β-glucosidase, alcohol dehydrogenase, and reductase might be involved in scent emission. Comprehensive GC-SIM analyses revealed that [1,2,2,2′,3′,4′,5′,6′-2H8]-2 and [1,2,2,2′,3′,4′,5′,6′-2H8]-3 must be biosynthesized from [1,2,2,2′,3′,4′,5′6′-2H8] l-phenylalanine ([2H8]-1) with a retention of the deuterium atom at α-position of [2H8]-1. 相似文献
86.
Thirteen pregnane glycosides were isolated from fresh leaves of Marsdenia tomentosa collected in the Fukuyama district. Of these, six were glycosides previously obtained from the same plant collected in the Fukuoka district and one from another Asclepiadaceous plant. The structures of the six new glycosides were determined by spectrometric method. 相似文献
87.
Single-bubble sonochemiluminescence in aqueous luminol solutions 总被引:1,自引:0,他引:1
Hatanaka S Mitome H Yasui K Hayashi S 《Journal of the American Chemical Society》2002,124(35):10250-10251
Sonochemiluminescence (SCL) of luminol due to a single bubble is studied through spectral measurement. No SCL was observed from a stable single bubble that emitted high-intensity sonoluminescence (SL). In contrast, SCL was observed under conditions of an unstable dancing bubble, where a bubble grows and ejects tiny bubbles, making it "dance" by counteraction. Furthermore, SCL was observed from dancing bubbles even when SL was not observed, depending on the dissolved gas content. The instability of bubble collapse is the key parameter governing SCL. 相似文献
88.
Masahiro Irie Setsuko Tomimoto Koichiro Hayashi 《Journal of polymer science. Part A, Polymer chemistry》1972,10(11):3243-3252
The photoinduced ionic polymerization of cyclohexene oxide was studied in the presence of pyromellitic dianhydride. The polymerization is initiated by the excited chargetransfer complex between cyclohexene oxide and the electron-acceptor and proceeds by a cationic mechanism. Photoinduced cationic polymerization of α-methylstyrene was also observed in the presence of pyromellitic dianhydride. The initiation mechanism of the polymerization was elucidated by means of electron spin resonance measurements. The concentration of pyromellitic dianhydride anion-radicals measured in this way was found to be proportional to the rate of polymerization. This result shows clearly that the photopolymerization is initiated by cation-radicals formed from photoexcited donoracceptor complexes. The attempted photocopolymerization of cyclohexene oxide and α-methylstyrene gave a mixture of homopolymers. The composition of the product depends on the wavelength of the light used. 相似文献
89.
The bis(dibutylstannylene) derivative of 1,2-cyclohexylidene-myo-inositol reacted with (S)-O-acetylmandeloyl chloride and diphosphate tetraesters to give 3,6-dimandelate and 3-phosphate, respectively. Using the stannylene methodology for the optical resolution and regioselective phosphorylation of the ketal, a concise synthesis of phosphatidylinositol with the natural configuration was accomplished. 相似文献
90.
Preparation and characterization of high-specific-surface-area activated carbons from K2CO3-treated waste polyurethane 总被引:2,自引:0,他引:2
Hayashi J Yamamoto N Horikawa T Muroyama K Gomes VG 《Journal of colloid and interface science》2005,290(2):437-443
An activated carbon with high specific surface area was prepared from polyurethane foam by chemical activation with K2CO3 and the influences of carbonization temperature and impregnation ratio on the pore structure of the prepared activated carbon were investigated. It was found that the specific surface area of the activated carbon was at a maximum value (about 2800 m(2)/g) at a carbonization temperature of 1073 K and at an impregnation ratio of 1.0. It was concluded that the polyurethane foam structure was modified during impregnation by K2CO3, K2CO3 promoted charring during carbonization, and then the weight loss behavior was changed below 700 and above 1000 K, carbon in the char was consumed by K2CO3 reduction, and this led to the high specific surface area. The prepared activated carbon had a very sharp micropore size distribution, compared with the commercial activated carbon having high specific surface area. The amounts of three organic vapors (benzene, acetone, and octane) adsorbed on the prepared activated carbons was much larger than those on the traditional coconut shell AC and the same as those on the commercial activated carbon except for octane. We surmised that the high specific surface area was due to the modification of the carbonization behavior of polyurethane foam by K2CO3. 相似文献